(N-Benzoyl-N′,N′-diphenylthioureato-κ2 S,O)(η4-cycloocta-1,5-diene)rhodium(I)
نویسندگان
چکیده
The title complex, [Rh(C(20)H(15)N(2)OS)(C(8)H(12))], exhibits an essentially square-planar coordination environment around the Rh(I) atom, which bears a bidentate cyclo-octa-diene ligand as well as a monoanionic bidentate benzoyl-thio-ureate ligand. The Rh(I) atom, the S- and O-donor atoms and the alkene centroids of the cyclo-octa-diene ligand do not deviate by more than 0.031 Å from their least mean-squares plane.
منابع مشابه
(N-Benzoyl-N′-phenylthiourea-κS)chlorido(η4-1,5-cyclooctadiene)rhodium(I)
The title compound, [RhCl(C(8)H(12))(C(14)H(12)N(2)OS)], is a rhodium(I) derivative with a functionalized thio-urea ligand. Despite the presence of several heteroatoms, the thio-urea ligand coordinates only in a monodentate fashion via the S atom. The geometry of the coordination sphere is approximately square planar about the Rh(I) atom, with two bonds to the π-electrons of the 1,5-cyclo-octa-...
متن کامل(+)-{1,2-Bis[(2R,5R)-2,5-dimethylphospholan-1-yl]ethane-κ2 P,P′}(η4-cycloocta-1,5-diene)rhodium(I) tetrafluoridoborate
The title compound, [Rh(C(8)H(12))(C(14)H(28)P(2))]BF(4), exhibits a rhodium(I) complex cation with a bidentate bis-phosphine ligand and a bidentate η(2),η(2)-coordinated cyclo-octa-1,5-diene. Together the ligands create a slightly distorted square-planar cordination environment for the Rh(I) atom. There are three mol-ecules in the asymmetric unit and intra-molecular P-Rh-P bite angles of 82.78...
متن کاملChlorido(η 4-cycloocta-1,5-diene)(N,N′-diethylthiourea-κS)rhodium(I)
In the title rhodium(I) complex, [RhCl(C(8)H(12))(C(5)H(12)N(2)S)], N,N'-diethyl-thio-urea acts as a monodenate S-donor ligand. The rhodium(I) coordination sphere is completed by the Cl atom and the COD [= 1,5-cyclo-octa-diene] ligand inter-acting through the π-electrons of the double bonds. If the midpoints of these two bonds are taken into account, the Rh atom exhibits a distorted square-plan...
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The title compound, [Rh2Br2(C8H12)2(C17H32N4)], was obtained by the reaction of 3,3'-(propane-1,3-di-yl)bis-(1-isopropyl-3,4,5,6-tetra-hydro-pyrimidin-1-ium) bromide and [{Rh(cod)Cl}2] (cod is cyclo-octa-1,5-diene) in tetra-hydro-furan. The two Rh(I) atoms each have a distorted square-planar coordination environment, defined by a bidentate cod ligand, a bromide anion and one C atom of the bridg...
متن کاملTris(N-benzoyl-N′,N′-diphenylthioureato-κ2 O,S)cobalt(III)
In the title compound, [Co(C(20)H(15)N(2)OS)(3)], the Co(III) atom is coordinated by the S and O atoms of three N-benzoyl-N',N'-diphenyl-thio-urea ligands in a slightly distorted octa-hedral geometry. The O and S atoms are in cis positions, while the positions between the O and S atoms are trans.
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عنوان ژورنال:
دوره 68 شماره
صفحات -
تاریخ انتشار 2012